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Friday, 25 October 2024

Abrasion Test

                                            Abrasion Test)

(Introduction):- The movement of traffic on the road causes excessive wear on the contact surface. When a vehicle moves on the road, the particles of soil present between the vehicle and the road produce particles. Powered vehicles with plows and wooden wheels also use the road. Therefore, for the construction of a good and durable road, it is necessary that the up resistance of its upper surface is high. For this, the stone soil used in road construction should be of high resistance so that it can tolerate the formation.

The hardness of the soil used in road construction i.e. abrasion resistance is determined by laboratory tests. There are the following three methods of gauge test in the laboratory- 

(1) Los Angeles abrasion test

(2) Table gauge test (Devel Abrasion test)

(3) Dorry Abrasion test


The Los Angel test is more popular for road works. 

2. Objective


Los angels abrasion test machine to determine the value of ballast and use it for road works.

3. Apparatus: As per IS 2386 (Part IV) - 1963 the description of the equipment is as follows


Type is-

  1. Los Angeles machine - It consists of a steel bolim with both ends closed, inner diameter 700 mm and length 500 mm. This I'm able to be rotated on a horizontal axis. To put ballast sample


gates


Rack


Saile

500mm-


Experimental part


Steel Cylinder


Shelves


Axis of rotation


Cover. Plates


Abrasive Charge and Aggregate                         

Support

Collecting Tray


Figure Log Angelus Machine



(H) Abrasion charge Twelve balls of 390 to 445 grams in diameter each, made of iron or steel, about 48 mm in diameter, are used as abrasion charges.


(iii) IS 170mm Sieve


(iv) Calling 5 to 10 kg capacity

v) Thermostatically controlled furnace


(vi) Tray

Oven)

4. Principle:

In this test, stones were used as ballast and steel balls were placed in the machine.


is put. Now by rotating this apan is generated on the soil. The process is due to the ballast hitting the balls and falling down from the top of the balls. This action will result in failure and wear and tear in the ballast, the less the gage resistance of the ballast will be. The wear resistance is expressed by the abrasion value.

Test Sample – 1.70 mm from chimney mine

Table [number] 1. 4. Principle In this test, the stone is placed in the ballast and steel balls in the machine.

is put. Now by rotating this apan is generated on the soil. The process is due to the ballast hitting the balls and falling down from the top of the balls. This action will result in failure and wear and tear in the ballast, the less the gauge resistance of the ballast will be. The wear resistance is expressed by the abrasion value. 

5. Procedure:

Test Sample – 1.70 mm Sieve\

Table [number]

 Principle: In this test, stones were used as ballast and steel balls were placed in the machine.


is put. Now by rotating this a pan is generated on the soil. The process is due to the ballast hitting the balls and falling down from the top of the balls. This action will result in failure and wear and tear in the ballast, the less the gage resistance of the ballast will be. The wear resistance is expressed by the abrasion value. 5. Procedure:


Test Sample – 1.70 mm from chimney mine

The coarse, clean soil sample is dried in a thermo-statically controlled oven at 105' - 110°C for four hours. The abdomen of the specimen is determined according to Table .

(i) Select the appropriate pending to be used for the test. As far as possible it should be similar to the pendis used in construction work. 

(ii) 5 kg for grading A, B, C and D and pending E, F and G For this take 10 kg sample. 

(iii) Select the value of abrasion charge according to the grade of the specimen from the following table.

Table No. 2 Selection of Abrasion Charge

(iv)   Open the lid of the container and drop the soil sample into the container. Close the lid tightly 

(v) Run the machine at 30 to 33 r. p. m. rotate at a uniform rate of (cycles per minute).

Experimental part

(vi) 500 cycles should be provided for painting A, B, C and D and 1000 cycles for painting E F and G. (vii) After rotating the desired cycle, the material is taken out by removing the protective cover.

(viii) Sieve these materials through a sieve of ARE 1-70 mm size and wash the suspended matter on it and improve it in water. 

(xi) Take the suspended material on the sieve with purity and take this weight out of the total sample in the material. Damage done known in percent


Do it (x) Test again by taking another sample and round off both the values ​​(to the nearest integer).


6. Calculations:



Where, W is the basic weight of the ballast specimen, W = IS 1-70m.m. Load after soil sample test stopped on conduction


Hence, the loss due to (W) – W. ).i.e sample taken and later sample weighed after abrasion for 500 cycles























8. Result:


Los Angeles Abrasion Value =

9. Precautions:


1. All equipment should be neat and clean.


2. There should be complete knowledge about the equipment before testing

3. Weight should be taken accurately.


4. The dustproof cover should be tightly closed before the test.


10. Analysis of Result:


Based on the results obtained, according to the specifications of the Indian Roads Congress, the suitability of ballast for different roads can be determined from the following table Above



Wednesday, 23 October 2024

EDTA --एथिलीनडायमिनेटेट्राएसेटिक एसिड (EDTA, एडेटेट कैल्शियम डिसोडियम, कैल्शियम डिसोडियम वर्सेनेट) एक केलेशन एजेंट है जिसका उपयोग भारी धातु विषाक्तता के लिए किया जाता है।


 EDTA --एथिलीनडायमिनेटेट्राएसेटिक एसिड (EDTA, एडेटेट कैल्शियम डिसोडियम, कैल्शियम डिसोडियम वर्सेनेट) एक केलेशन एजेंट है जिसका उपयोग भारी धातु विषाक्तता के लिए किया जाता है।

EDTA घोल कैसे तैयार करें

मानक EDTA घोल का उपयोग करके पानी की कुल कठोरता का अनुमान

उद्देश्य: दिए गए पानी के नमूनों की कुल कठोरता का निर्धारण करें। परिचय: पानी में कठोरता कैल्शियम और मैग्नीशियम के घुले हुए लवणों की उपस्थिति के कारण होती है। 

यह पीने, नहाने, धोने के लिए अनुपयुक्त है और यह कैल्शियम और मैग्नीशियम आयनों के स्केल भी बनाता है। 

इसे उबालकर आसानी से हटाया जा सकता है। 

स्थायी कठोरता कैल्शियम और मैग्नीशियम आयनों के क्लोराइड और सल्फेट की उपस्थिति के कारण होती है। 

बॉयलर में इस प्रकार की कठोरता। इसलिए पानी के नमूने में मौजूद कठोरता पैदा करने वाले पदार्थों की मात्रा का अनुमान लगाना आवश्यक है। 

एक बार इसका अनुमान लगाने के बाद, पानी के उपचार के लिए आवश्यक रसायनों की मात्रा की गणना की जा सकती है। कठोरता का अनुमान कॉम्प्लेक्सोमेट्रिक अनुमापन पर आधारित है। 


पानी की कठोरता एथिलीन डायमाइन टेट्रा एसिटिक एसिड (EDTA) के एक मानक घोल के साथ अनुमापन करके निर्धारित की जाती है, जो एक जटिल एजेंट है। 

चूंकि EDTA पानी में अघुलनशील है, इसलिए इस प्रयोग के लिए EDTA का डाइसोडियम नमक लिया जाता है। 

EDTA एक ​​धातु आयन के साथ चार या छह समन्वय बंध बना सकता है। 

पानी में दो प्रकार की कठोरता मौजूद होती है, पहली अस्थायी कठोरता और दूसरी स्थायी कठोरता। अस्थायी कठोरता बाइकार्बोनेट की उपस्थिति के कारण होती है जिसे उबालने से हटाया नहीं जा सकता। 

आवश्यकताएँ: पानी का नमूना ब्यूरेट 25-30 मिली ग्लास की कीप पिपेट 

1 मिली फ्लास्क ड्रॉपर मापने का सिलेंडर अभिकर्मक: EDTA, एरियोक्रोम ब्लैक-टी, NH2CL, अमोनिया बफर 

2. एरियोक्रोम ब्लैक-टी: 0.4 ग्राम एरियोक्रोम ब्लैक टी, 4.5 ग्राम हाइड्रॉक्सिलमाइन हाइड्रोक्लोराइड को 100 मिली 95% एथिल अल्कोहल में मिलाएं। 

3. अमोनिया बफर: स्टॉक ए: 143 मिली सांद्र NH4OH में 16.9 ग्राम NH4CL, स्टॉक बी: 50 मिली आसुत जल में 1.25 ग्राम EDTA का मैग्नीशियम लवण घोलें। दोनों स्टॉक घोल को मिलाएं और DDW के साथ 250 मिली तक पतला करें। 

10 मिली घोल को DDW के साथ 100 मिली तक पतला करें। प्रक्रिया: 

1. बुरेट को मानक EDTA घोल से शून्य स्तर तक भर दिया जाता है। 

2. फ्लास्क में 50 मिली नमूना पानी लें 

5. प्रारंभिक रीडिंग नोट करें।

6. EDTA घोल के विरुद्ध सामग्री का अनुमापन करें। अंतिम बिंदु पर रंग वाइन लाल से नीले रंग में बदल जाता है। 

7. अंतिम रीडिंग नोट करें और उसे रिकॉर्ड करें। प्रक्रिया को तब तक दोहराएं जब तक हमें संगत मान न मिल जाए। 

8. दूसरे फ्लास्क में 50 मिली सैंपल लें और उसे उबालें। (पानी की अंतिम मात्रा प्राप्त करने के लिए आसुत जल डालें।) 

9. चरण 3-7 को दोहराएं। 

गणना: क्रम संख्या पानी का नमूना (50ml) आरंभिक मान अंतिम मान EDTA का मिली 1 2 3 पानी की कुल कठोरता mg/L (CaCO3 स्केल) = इस्तेमाल किया गया EDTA का मिली (बिना उबाला हुआ) 

*103 /ml नमूने पानी की स्थायी कठोरता mg/L (CaCO3 स्केल) = इस्तेमाल किया गया EDTA का मिली (उबला हुआ) *103 /ml नमूने पानी की अस्थायी कठोरता mg/L (CaCO3 स्केल) = पानी की कुल कठोरता - पानी की स्थायी कठोरता अवलोकन: घुलनशील आसुत जल और R.O पानी का रंग तुरंत नीला हो गया, जबकि नल का पानी और तालाब का पानी एरिक्रोम ब्लैक टी मिलाने पर वाइन रेड हो गया और इसलिए EDTA घोल के साथ अनुमापन करने पर नीला हो गया

Tuesday, 22 October 2024

Total Hardness of given water sample by EDTA Titrimetric Method.


Total Hardness of given water sample by EDTA Titrimetric Method.

The Hardness of Water


In general definition, the hardness of water is described as a measurement of the capacity of water to precipitate soap. Water hardness level is a parameter that is very important in water quality analysis.

Soap is mainly precipitated by Calcium ions and Magnesium ions. Also, some other polyvalent cations also have the ability to precipitate soap. But those cations are normally in a complex form with organic compounds. Therefore, their role in the hardness of water is negligible and very difficult to measure.

So, the total hardness of water is defined as the total amount of calcium and magnesium ion concentrations. Both are stated as calcium carbonate, in milligrams per liter unit. Hardness water samples are determined by EDTA Titrimetric Method.

Other than the total hardness of water there is “Carbonate hardness”. Carbonate hardness is also known as carbonate and bicarbonate alkalinity. In carbonate hardness, we measure the milligrams of carbonate and bicarbonate ions dissolved in one liter of water. 


Numerically, Total hardness is always greater than carbonate hardness. The excess amount is the total hardness is the non-carbonate hardness. Sometimes carbonate hardness may equal the total hardness. That means there is no non-carbonate hardness present.

The total hardness of water can be zero to several hundred milligrams per liter according to the water sample. Generally, water can be categorized according to its hardness as follows.

Category

Total hardness (mg/l)

Soft water

0 – 60

Moderately hard water

61 – 120

Hard water

121 – 180

Very hard

>180

Table 01: Categories of water based on the hardness

EDTA titrimetric method of determining the total hardness of water

Ca2+ and Mg2+ ions in the water sample are titrated with Ethylenediaminetetraacetic acid (EDTA) at 10.0 ± 0.1 pH. We use the Eriochrome black T as the indicator here.

First, use the Eriochrome black T indicator will be complexed with Ca2+ and Mg2+ ions in the water. So, the sample is wine red in color. When it is titrated with EDTA, metal ions are complexed with EDTA, and the solution becomes blue in color. At pH = 10,

Reagents

       I.            Buffer solution

             o     Prepared by dissolving 16.9 g of ammonium chloride (NH4Cl) in 143 mL of conc. ammonium hydroxide (NH4OH).

             o     Then this solution is added 1.25 g of magnesium salt of EDTA and diluted to 250 ml with distilled water.

    II.            Eriochrome Black T indicator

 III.            Standard EDTA titrant

             o     To prepare 0.01M of standard EDTA titrant 3.723 g analytical reagent-grade disodium ethylenediaminetetraacetate dihydrate, also called (ethylenedinitrilo) tetraacetic acid disodium salt (EDTA) is dissolved in distilled water.

             o     This solution is diluted to 1000 mL.

IV.            Standard calcium solution

             o     Standard CaCO3 solution is used to standardize the prepared EDTA solution.

             o     First, 1000 mg (1g) of anhydrous CaCO3 is dissolved in 1+1 HCl. In 1+1 HCl there are one volume of concentrated HCl and 1 volume of distilled water.

             o     After dissolving CaCO3, it is added 200 mL of distilled water and boiled for a few minutes. The purpose of boiling is to expel CO2.

             o     Then the solution let to be cooled. The cooled solution is added with a few drops of methyl orange indicator and adjusted to the intermediate orange color by adding 1 + 1 HCl, as required.

             o     Finally. The solution is diluted to 1000 mL with distilled water. 1 mL of this solution has 1.00 mg of CaCO3.

   V.            Sodium hydroxide (NaOH), 0.1N

             o     Reagent-grade solution of NaOH is used.

Procedure

25 mL of the test solution is taken and it is diluted to 50 mL by adding 25 mL of distilled water. Then add 1- 2 mL of prepared buffer solution. About 1 – 2 drops of indicator solution are added to the sample. If the indicator is used as a dry powder, use about 1mg of the indicator.

When the indicator is added solution becomes a wine-red color. Then the sample is titrated with the standard EDTA solution. The color at the endpoint is blue.

As the sample is diluted with distilled water, a blank titration should be taken place. Because sometimes it may have Ca2+ and Mg2+ ions in distilled water. The endpoint value of the blank titration should be subtracted from the sample endpoint in the final calculations.

Calculation 


According to the stoichiometry Ca2+ and Mg2+ ions react with EDTA at a 1:1 ratio. Therefore, mols of EDTA equals the total mols of Ca2+ and Mg2+ ions. To get the EDTA volume consumed by ions in the sample we should subtract the endpoint value of the blank titration from the endpoint value of the sample titration.

The hardness of water is expressed as the milligrams of CaCO3 in 1 liter of sample. Therefore,

A volume of 25 mL of the sample was taken for titration. To calculate the mass present in the 1 L of the sample,

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